Early solar system aqueous activity: K isotope evidence from Allende     

Yun Jiang  Piers Koefoed  Olga Pravdivtseva  Heng Chen  Chun‐Hui Li  Fang Huang  Li‐Ping Qin  Jia Liu  Kun Wang 《Meteoritics & planetary science》2021,56(1):61-76

The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K₂O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ⁴¹K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K₂O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ⁴¹K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K₂O content and K isotope compositions (0.02–0.05 wt%; δ⁴¹K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation.  相似文献   

Using hysteretic behaviour and hydrograph classification to identify hydrological function across the “hillslope–depression–stream” continuum in a karst catchment     

Runrun Zhang  Xi Chen  Zhicai Zhang  Chris Soulsby 《水文研究》2020,34(16):3464-3480

In cockpit karst landscapes, fluxes from upland areas contribute large volumes of water to low-lying depressions and stream flow. Hydrograph hysteresis and similarity between monitoring sites is important for understanding the space–time variability of hydrologic responses across the “hillslope–depression–stream” continuum. In this study, the hysteretic feature of hydrographs was assessed by characterizing the loop-like relationships between responses at upstream sites relative to subsurface discharge at the outlet of a small karst catchment. A classification of hydrograph responses based on the multi-scale smoothing Kernel -derived distance classifies the hydrograph responses on the basis of similarities between hillslope and depression sites, and those at the catchment outlet. Results demonstrate that the temporal and spatial variability of hydrograph hysteresis and similarity between hillslope flow and outlet stream flow can be explained by the local heterogeneity of depression aquifer. Large depression storage deficits emerging in the highly heterogeneous aquifer produce strong hysteresis and multiple relationships of upstream hydrographs relative to the outlet subsurface discharge. In contrast, when depression storage deficits are filled during consecutive rainfall events, depression hydrographs at the high permeability sites are almost synchronous or exhibit a monotonous function with the hydrographs at the outlet. This reduced hydrograph hysteresis enhances preferential flow paths in fractured rocks and conduits that can accelerate the hillslope flow to the outlet. Therefore, classification of hydrograph similarities between any upstream sites and the catchment outlet can help to identify the dominant hydrological functions in the heterogeneous karst catchment.  相似文献   

Investigation of the elevation of saltwater wedge due to subsurface dams     

Qinpeng Chang  Tianyuan Zheng  Youyuan Chen  Xilai Zheng  Marc Walther 《水文研究》2020,34(22):4251-4261

Subsurface dams are rather effective and used for the prevention of saltwater intrusion in coastal regions around the world. We carried out the laboratory experiments to investigate the elevation of saltwater wedge after the construction of subsurface dams. The elevation of saltwater wedge refers to the upward movement of the downstream saltwater wedge because the subsurface dams obstruct the regional groundwater flow and reduce the freshwater discharge. Consequently, the saltwater wedge cannot further extend in the longitudinal direction but rises in the vertical profile resulting in significant downstream aquifer salinization. In order to quantitatively address this issue, field-scale numerical simulations were conducted to explore the influence of various dam heights, distances, and hydraulic gradients on the elevation of saltwater wedge. Our investigation shows that the upward movement of the saltwater wedge and its areal extension in the vertical domain of the downstream aquifer become more severe with a higher dam and performed a great dependence on the freshwater discharge. Furthermore, the increase of the hydraulic gradient and the dam distance from the sea boundary leads to a more pronounced wedge elevation. This phenomenon comes from the variation of the freshwater discharge due to the modification of dam height, location, and hydraulic gradient. Large freshwater discharge can generate greater repulsive force to restrain the elevation of saltwater wedge. These conclusions provide theoretical references for the behaviour of the freshwater–seawater interface after the construction of subsurface dams and help optimize the design strategy to better utilize the coastal groundwater resources.  相似文献   

城市内涝灾害受灾人口评估方法与实证研究：以哈尔滨市道里区为例     

陈鹏  赵洪阳  张继权  张硕  鲍建华  刘晓静 《地理科学》2020,40(1):158-164

城市内涝灾害频发,对居民生命安全造成严重威胁,为提高城市内涝灾害受灾人口评估精度,提出一种更为精确的受灾人口评估方法。以哈尔滨市道里区为研究区,以城市内涝灾害受灾人口为研究对象,运用一、二维非恒定流为主控方程,构建城市内涝数值模拟模型,并结合受灾人口分布特点,综合构建基于土地利用的人口随时间变化的计算模型。实现在模拟内涝灾害影响范围基础上,利用受灾人口计算模型提取白天与夜晚受灾人口分布情况。结果表明：研究区在百年一遇降雨情景下,有25条街道会发生不同程度积水,积水深度范围值为0.10~1.42 m;此级别内涝灾害在白天11条街道受灾人口数量最大值达到3 500人,夜晚10条街道受灾人口数量最大值为720人。  相似文献   

万维望远镜平台下基于ASSURE模式的天文教学研究     

黄子义 《地理教学》2020,(3):62-64,52

随着教学手段和教学方法的现代化,信息技术与课程整合正成为教育改革的研究热点。文章以万维望远镜(WWT)平台为教学媒体,以ASSURE模式为教学设计的理论依据,设计并构建用以指导天文教学准备、实施与评价的教学模式,并将该模式应用于“四季星空”的教学案例中,使用基于信息技术的互动分析编码系统和学生课程反馈调查对教学效果进行分析和评价。研究表明,万维望远镜的使用可以降低教师言语比率,改变传统天文教学中以讲授式为主的教学方式。它适合起点能力较高、对新知识和新技能掌握能力较强的学生,能提高其学习兴趣和积极性,激发其探索宇宙的兴趣,有助于培养学生的科学素养。  相似文献   

乡土地理实践活动案例分析与应用——以“明光市女山古火山地质公园考察”为例     

孙玉林  陈荟 《地理教学》2020,(2):30-32

地理实践是地理科学的重要研究方法,也是中学地理学科的主要学习方式之一。中学地理实践活动应结合乡土地理资源,充分挖掘当地可供考察的自然、人文素材,形成丰富的乡土地理实践案例。本文以“女山古火山地质公园实践活动为案例”,探究乡土资源在地理实践活动中的应用。  相似文献   

贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

乡村空间重构的理论研究进展与理论框架构建     

金利霞  文志敏  范建红  杜志威 《热带地理》2020,40(5):765-774

在新时代城乡融合发展、乡村地域人地关系日益复杂的背景下，乡村空间重构成为乡村地理学研究的重要课题。西方“后生产主义”语境下，乡村空间研究开始出现消费转向、社会-文化转向和后现代转向，多功能、全球化乡村转型与空间重构研究成为西方乡村空间研究的热点；国内研究主要基于乡村地理学人地关系地域系统理论展开乡村空间重构过程—机理—调控研究以及微观视角下农户经济空间行为研究；当前，中国乡村空间重构呈现自上而下的政治经济学转型特征，具有中国特色的农村集体组织与政府、企业、个人等其他主体之间的空间-权力关系成为乡村空间重构的重要视角。政治经济地理学及“社会-空间”二元辩证法为乡村空间重构研究提供了很好的研究范式与研究方法，乡村空间重构研究应系统整合空间生产、主体能动性、土地资本化、社会关系网络、人地关系地域系统和农户地理等政治经济学、地理学理论，强化自然、经济、社会和文化等多要素相互作用及其空间响应机制研究，重点开展多要素多维度的乡村空间格局形成及演变规律研究、乡村社会空间再生产研究、能动性视角下乡村劳动力空间生产研究、政府政策制度与城乡空间治理体系创新研究。  相似文献   

两株南极枝孢霉属真菌Cladosporium sp.NJF4和NJF6的次级代谢产物研究          下载免费PDF全文

常俊男  田晓清  樊成奇  黄金昌  陆亚男  韩清华 《极地研究》2020,32(1):60-67

南极因其独特的自然环境成为潜在、重要的微生物资源库,是产生新型生物活性物质和先导化合物菌株的潜在种源地,南极微生物正在成为创新药物研究新的重要资源。虽然近年来对南极微生物次级代谢产物的研究逐渐增加,但与温带和热带微生物研究相比仍处于初级阶段。对从南极普里兹湾海洋沉积物中获得的两株枝孢霉属真菌Cladosporium sp. NJF4和NJF6进行次级代谢产物分离及结构鉴定,获得20个化合物。化合物结构类型包括甾醇(1)、倍半萜类(7—8)、生物碱类(9—14)、二酮哌嗪(2—5、15—17)、芳香酸(6、18—19)等,其中倍半萜类(7—8)为首次从枝孢霉属真菌中分离得到,以上研究将为丰富南极微生物次级代谢产物库奠定一定的研究基础。  相似文献   

三元插层材料的合成及其在聚丙烯老化中的应用          下载免费PDF全文

郭凡  刘志启  王庭胜  李丽娟  李娜 《盐湖研究》2020,28(3)

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料，以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH)，通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌，探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中，制备MgNiFe-LDH/PP复合材料，通过对材料的加速老化测其力学性能，研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明，当Mg2+:Ni2+:Fe3+=2:1:1，反应温度为140℃、陈化时间为24 h时，合成的MgNiFe-LDH为片状，形貌较为规整，颗粒粒径约为2μm；经加速老化后，填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP，当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变，可明显提高PP的抗老化性能。  相似文献